Yifu Shi, et al. Appl. Phys. Lett. 2023; 123 (26): 261106.
☐ The work investigates passivating‐contact stacks for solar cells; specifically thin film contact structures comprising e.g. poly-Si on SiOx.
☐ ToF-ERDA employed to directly detect and depth‐profile hydrogen (and deuterium) in these thin‐film stacks.
☐ The study shows that ToF-ERDA can resolve H/D. Artifact issues common to other techniques (e.g., SIMS) are mitigated by ToF-ERDA.
☐ Annealing treatments change the H/D distribution and that these changes correlate with passivation quality improvements. For example, H/D removal or redistribution is linked to changes in the interface oxide and poly‐Si structure.
☐ The work addresses decontamination of infrastructure surfaces (specifically stainless steel pipes) that are contaminated by firefighting foams containing Per‐ and polyfluoroalkyl substances (PFAS).
☐ Time‐of‐Flight Elastic Recoil Detection Analysis (ToF-ERDA) is applied to analyse the pipe surfaces after different cleaning procedures. It enabled measurement of remaining fluorine (F) on the interior surfaces.
☐ ToF-ERDA results confirmed that even after cleaning there remained residual fluorine on the pipe surfaces (including deeper in the surface layers).
☐ The depth‐profiling capability of ToF-ERDA added critical insight about what’s left behind on surfaces.
☐ ToF-ERDA was used to quantitatively analyse elemental composition (especially light organic species such as H, C, N) and depth profiles in the perovskite layers before and after proton irradiation.
☐ ToF-ERDA played a central diagnostic role in this work, enabling:
☐ Accurate quantification of elemental loss (H, C, N) due to irradiation;
☐ Verification that PDAI₂ mitigates organic volatilisation;
☐ Support for the proposed mechanism of radiation-induced defect passivation and lattice stabilization.
☐ Micro‐crystalline vs nano‐crystalline ZrN (zirconium nitride) thin films respond to radiation (ion beam or other irradiation) in terms of structural and compositional changes.
☐ The study applied ToF-ERDA to probe changes in elemental composition (particularly light elements like O, N) and depth distribution caused by radiation in the films.
☐ The findings suggest that nano‐crystalline ZrN is more susceptible to oxidation under irradiation than the micro‐crystalline form, and that the distribution of oxygen and nitrogen evolves differently in both forms.
Luke.Antwis@surrey.ac.uk
+44 (0)1483 689145
Surrey Ion Beam Centre,
University of Surrey,
Guildford, Surrey,
GU2 7XH, UK.
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Ion Beam Induced Current (IBIC) : Measures the charge collection efficiency or current generated in an electronic or semiconductor device when irradiated with an ion beam. IBIC provides spatially resolved maps of electrical activity, carrier transport, and radiation damage, enabling the evaluation of detector performance and semiconductor device integrity.

Ion Beam Induced Luminescence (IBIL) : Detects visible or near-visible photons emitted from the sample as a result of ion excitation. The luminescence spectrum reveals information about electronic structure, impurities, and defect states, making IBIL a valuable tool for studying semiconductors, minerals, and scintillating materials.

Scanning Transmission Ion Microscopy (STIM) : Uses a finely focused MeV ion beam scanned across a thin specimen. By measuring the energy loss or transmitted particle intensity, STIM provides quantitative two-dimensional or three-dimensional maps of areal density and thickness at sub-micrometer spatial resolution. It is particularly useful for biological samples, thin films, and microelectronic structures.

MeV Secondary Ion Mass Spectrometry (MeV-SIMS) : Combines the principles of SIMS with high-energy (MeV) primary ions. The electronic stopping processes at these energies produce significantly higher secondary ion yields with minimal fragmentation, allowing for molecular analysis while preserving depth resolution. MeV-SIMS bridges the gap between traditional SIMS and nuclear-based IBA, offering chemical and molecular information alongside elemental quantification.

Nuclear Reaction Analysis (NRA) : Uses specific nuclear reactions to identify and quantify elements with high sensitivity.

Elastic Recoil Detection Analysis (ERDA) : Detects atoms recoiling from the surface after ion impact, particularly useful for quantifying light elements such as hydrogen.

Particle-Induced X-ray Emission (PIXE) : Detects characteristic X-rays emitted when the incident ions ionize inner-shell electrons, allowing for multi-elemental analysis with high sensitivity.

Rutherford Backscattering Spectrometry (RBS): Measures the energy of ions scattered elastically from nuclei, providing information on elemental composition and depth distribution.
