Time of Flight Elastic Recoil Detection Analysis (ToF-ERDA)
Matthew Sharpe & Callum McAleese

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Yifu Shi, et al. Appl. Phys. Lett. 2023; 123 (26): 261106.

DOI: https://doi.org/10.1063/5.0174131

Desorption electrospray ionisation (DESI) and particle induced X-ray emission (PIXE)

☐  The work investigates passivating‐contact stacks for solar cells; specifically thin film contact structures comprising e.g. poly-Si on SiOx.
☐  ToF-ERDA employed to directly detect and depth‐profile hydrogen (and deuterium) in these thin‐film stacks.
☐  The study shows that ToF-ERDA can resolve H/D. Artifact issues common to other techniques (e.g., SIMS) are mitigated by ToF-ERDA.
☐   Annealing treatments change the H/D distribution and that these changes correlate with passivation quality improvements. For example,            H/D removal or redistribution is linked to changes in the interface oxide and poly‐Si structure.

Decontamination and Surface Analysis of PFAS-Contaminated Fire Suppression System Pipes: Effects of Cleaning Agents and Temperature

☐  The work addresses decontamination of infrastructure surfaces               (specifically stainless steel pipes) that are contaminated by                     firefighting foams containing Per‐ and polyfluoroalkyl substances           (PFAS).
☐  Time‐of‐Flight Elastic Recoil Detection Analysis (ToF-ERDA) is                   applied  to analyse the pipe surfaces after different cleaning                   procedures. It enabled measurement of  remaining fluorine (F) on           the interior surfaces.
☐  ToF-ERDA results confirmed that even after cleaning there remained       residual fluorine on the pipe surfaces (including deeper in the                 surface layers).
☐  The depth‐profiling capability of ToF-ERDA added critical insight             about what’s left behind on surfaces.

Perovskite solar cells for space applications

☐  ToF-ERDA was used to quantitatively analyse elemental composition       (especially light organic species such as H, C, N) and depth profiles         in the perovskite layers before and after proton irradiation.

☐   ToF-ERDA played a central diagnostic role in this work, enabling:
       ☐  Accurate quantification of elemental loss (H, C, N) due to                          irradiation;
       ☐  Verification that PDAI₂ mitigates organic volatilisation;
       ☐  Support for the proposed mechanism of radiation-induced                      defect passivation and lattice stabilization.

Radiation effects on nuclear surrogate material

☐  Micro‐crystalline vs nano‐crystalline ZrN (zirconium nitride) thin               films respond to radiation (ion beam or other irradiation) in terms of       structural and compositional changes.
☐  The study applied ToF-ERDA to probe changes in elemental                     composition (particularly light elements like O, N) and depth                   distribution caused by radiation in the films.
☐  The findings suggest that nano‐crystalline ZrN is more susceptible           to oxidation under irradiation than the micro‐crystalline form, and         that the distribution of oxygen and nitrogen evolves differently in           both forms.

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